| Title | Direct conversion of N_2 and O_2:status,challenge and perspective |
| Authors | Di Li Lingxing Zan Shiming Chen Zhang-Jie Shi Ping Chen Zhenfeng Xi Dehui Deng |
| Affiliation | State Key Laboratory of Catalysis,Collaborative Innovation Center of Chemistry for Energy Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Department of Chemistry, Fudan University Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Beijing National Laboratory for Molecular Sciences(BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry,Peking University |
| Keywords | key components of air conversion of N_2 and O_2 NO_x synthesis C-N-O organics |
| Issue Date | 31-Dec-2022 |
| Publisher | National Science Review |
| Abstract | As key components of air,nitrogen(N_2) and oxygen(O_2) are the vital constituents of lives.Synthesis of NO_2,and C-N-O organics direct from N_2 and O_2,rather than from an intermediate NH_3(known as the Haber-Bosch process),is tantalizing.However,the extremely strong N≡N triple bond(945 kJ mol~(-1)) and the nonpolar stable electron configuration of dinitrogen lead to its conversion being extensively energy demanding.The further selective synthesis of high-value C-N-O organics directly from N_2,O_2 and C-containing molecules is attractive yet greatly challenging from both scientific and engineering perspectives.Enormous efforts have been dedicated to the direct conversion of N_2 and O_2 via traditional and novel techniques,including thermo chemical,plasma,electrochemical,ultrasonic and photochemical conversion.In this review,we aim to provide a thorough comprehension of the status and challenge of the direct conversion of N_2,O_2 and C-containing molecules(particularly N_2 and O_2).Moreover,we will propose some future perspectives to stimulate more inspiration from the scientific community to tackle the scientific and engineering challenges. |
| URI | http://hdl.handle.net/20.500.11897/669971 |
| ISSN | 2095-5138 |
| Indexed | 中国科学引文数据库(CSCD) |
| Appears in Collections: | 化学与分子工程学院 北京分子科学国家实验室 生物有机与分子工程教育部重点实验室 |
