| Title | Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation |
| Authors | Jin, Yigang Fang, Yuhui Li, Ze Hao, Xiang He, Feng Guan, Bo Wang, Dongwei Wu, Sha Li, Yang Liu, Caiming Dai, Xiaojuan Zou, Ye Sun, Yimeng Xu, Wei |
| Affiliation | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China Univ Chinese Acad Sci, Beijing 100049, Peoples R China Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing Key Lab Magnetoelect Mat & Devices, Beijing 100871, Peoples R China Natl Ctr Nanosci & Technol, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China |
| Keywords | TRANSITION TRANSPORT LIV2O4 |
| Issue Date | 22-Oct-2022 |
| Publisher | NATURE COMMUNICATIONS |
| Abstract | Organic metal chalcogenides (OMCs) are organic-inorganic hybrid materials with continuous M-X (X = S, Se, Te) networks that are covalently connected by organic ligands. Here authors report a family of bimetallic OMCs synthesized via selective metal metathesis and oxidation transformation. Conducting organic metal chalcogenides (OMCs) have attracted considerable interest for their superior electrical properties and fascinating functions. However, the electronic structural and functional regulation of OMCs are typically limited to the combination of monometallic nodes and graphene-like ligands. Here, we report a family of bimetallic OMCs ([CuAgx(C6S6)](n), x = 4 or 2) synthesized via selective metal metathesis and oxidation transformation. Both OMCs have alternatively stacked one-dimensional (1D) copper-dithiolene chains and 2D Ag-S networks, which can synergistically serve as charge transport pathways, rendering these bimetallic materials highly conductive. The incorporation of heterometallic nodes turned nonmagnetic [Ag-5(C6S6)](n) into paramagnetic metallic [CuAg4(C6S6)](n), which exhibited a coherence-incoherence crossover in magnetic susceptibility measurements and an unusually large Sommerfeld coefficient, reminiscent of the characteristics of Kondo lattice. This work opens up an avenue for tailoring the electronic structures of OMCs and provides a platform for studying the dichotomy between electronic localization and itinerancy. |
| URI | http://hdl.handle.net/20.500.11897/657643 |
| DOI | 10.1038/s41467-022-34118-7 |
| Indexed | SCI(E) |
| Appears in Collections: | å å¦ä¸ å å å·¥ç¨ å¦é ¢ |
