Title Self-Assemblies and Properties of Side-On Picene Strips on a Monolayered CuO Film
Authors Peng, Zhantao
Di, Bin
Zhao, Xinwei
Lin, Yuxuan
Diao, Mengxiao
Xu, Zhen
Guo, Weijun
Zhou, Xiong
Chen, Qiwei
Wang, Yongfeng
Wu, Kai
Affiliation Peking Univ, Coll Chemistr y & Mol Engn, BNLMS, Beijing 100871, Peoples R China
Peking Univ, Dept Elect, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China
Keywords GRAPHENE NANORIBBONS
SINGLE-ATOMS
THIN-FILMS
SURFACE
MOLECULE
Issue Date Oct-2022
Publisher JOURNAL OF PHYSICAL CHEMISTRY C
Abstract Thermally deposited picene (C22H14) molecules on a monolayered CuO film were grown at a Cu(110) self-assemble into side-on molecular strips extending along the [1 (1) over bar0] direction, as revealed by scanning tunneling microscopy (STM). The picene molecules are closely stacked on and anchored to the Cu-O chains via their armchair edges. They form two stacking modes and stick to the substrate via their long (Pic-I) and short (Pic-II) armchair edges. Such configurations are reversibly switchable by either an applied STM bias voltage pulse or continuous tip navigation. Scanning tunneling spectroscopies acquired above the Pic-I and Pic-II strips reveal different electronic states, showing a clear relationship between their electronic structures and their stacking modes on the substrate.
URI http://hdl.handle.net/20.500.11897/655845
ISSN 1932-7447
DOI 10.1021/acs.jpcc.2c05723
Indexed EI
SCI(E)
Appears in Collections: å å¦ä¸ å å å·¥ç¨ å¦é ¢
电子学院
纳米器件物理与化学教育部重点实验室

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