Title | Self-Assemblies and Properties of Side-On Picene Strips on a Monolayered CuO Film |
Authors | Peng, Zhantao Di, Bin Zhao, Xinwei Lin, Yuxuan Diao, Mengxiao Xu, Zhen Guo, Weijun Zhou, Xiong Chen, Qiwei Wang, Yongfeng Wu, Kai |
Affiliation | Peking Univ, Coll Chemistr y & Mol Engn, BNLMS, Beijing 100871, Peoples R China Peking Univ, Dept Elect, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China |
Keywords | GRAPHENE NANORIBBONS SINGLE-ATOMS THIN-FILMS SURFACE MOLECULE |
Issue Date | Oct-2022 |
Publisher | JOURNAL OF PHYSICAL CHEMISTRY C |
Abstract | Thermally deposited picene (C22H14) molecules on a monolayered CuO film were grown at a Cu(110) self-assemble into side-on molecular strips extending along the [1 (1) over bar0] direction, as revealed by scanning tunneling microscopy (STM). The picene molecules are closely stacked on and anchored to the Cu-O chains via their armchair edges. They form two stacking modes and stick to the substrate via their long (Pic-I) and short (Pic-II) armchair edges. Such configurations are reversibly switchable by either an applied STM bias voltage pulse or continuous tip navigation. Scanning tunneling spectroscopies acquired above the Pic-I and Pic-II strips reveal different electronic states, showing a clear relationship between their electronic structures and their stacking modes on the substrate. |
URI | http://hdl.handle.net/20.500.11897/655845 |
ISSN | 1932-7447 |
DOI | 10.1021/acs.jpcc.2c05723 |
Indexed | EI SCI(E) |
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