Title | Excitation-Dependent Luminescence of 0D ((CH3)(4)N)(2)ZrCl6 across the Full Visible Region |
Authors | Dai, Guangkuo Ma, Zhimin Qiu, Yixin Li, Zewei Fu, Xiaohua Jiang, Hong Ma, Zhiyong |
Affiliation | Beijing Univ Chem Technol, Coll Chem Engn, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China Peking Univ, Coll Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
Keywords | HALIDE PEROVSKITES EMISSION |
Issue Date | Aug-2022 |
Publisher | JOURNAL OF PHYSICAL CHEMISTRY LETTERS |
Abstract | Herein, we report a novel hybrid organic-inorganic Zr(IV) metal halide ((CH3)(4)N)(2)ZrCl6, which demonstrates fascinating excitation-dependent luminescence across the full visible region. The single crystal of ((CH3)(4)N)(2)ZrCl6 showed an unexpected high degree of symmetry and formed a unique 0D structure with isolated [ZrCl6](2-) octahedrons. Amazingly, three different emission groups emerged under changeable excitation light. The first emission group peaked at 462 nm with a ns lifetime and a mu s lifetime, which is assigned to free-exciton fluorescence and thermally activated delayed fluorescence (TADF). The second group of emissions featured elaborate multipeak light-emitting components, which is ascribed to the d-d transitions of Zr(IV). The third emission group centered at 660 nm was attributed to the typical self-trapped exciton (STE) emission. To our best knowledge, this work for the first time reports a 0D organic-inorganic metal halide with distinctive excitation-dependent full-visible-spectrum luminescence via four different emission mechanisms. |
URI | http://hdl.handle.net/20.500.11897/650545 |
ISSN | 1948-7185 |
DOI | 10.1021/acs.jpclett.2c015617553J |
Indexed | SCI(E) |
Appears in Collections: | 工学院 |