Title Unravelling Alkali-Metal-Assisted Domain Distribution of Quasi-2D Perovskites for Cascade Energy Transfer toward Efficient Blue Light-Emitting Diodes
Authors Cai, Wanqing
Ali, Muhammad Umair
Liu, Ping
He, Miao
Zhao, Cong
Chen, Ziming
Zang, Yue
Tang, Man-Chung
Meng, Hong
Fu, Hongyan
Wei, Guodan
Yip, Hin-Lap
Affiliation Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst TBSI, Shenzhen 518055, Peoples R China
Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Sch Mat Sci & Engn, 381 Wushan Rd, Guangzhou 510640, Peoples R China
Peking Univ, Sch Adv Mat, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon, Hong Kong 999077, Peoples R China
City Univ Hong Kong, Sch Energy & Environm, Kowloon, Hong Kong 999077, Peoples R China
Keywords LEAD-HALIDE PEROVSKITES
HIGH-PERFORMANCE
SOLAR-CELLS
NANOCRYSTALS
PASSIVATION
DYNAMICS
DESIGN
Issue Date May-2022
Publisher ADVANCED SCIENCE
Abstract Solution processable quasi-2D (Q-2D) perovskite materials are emerging as a promising candidate for blue light source in full-color display applications due to their good color saturation property, high brightness, and spectral tunability. Herein, an efficient energy cascade channel is developed by introducing sodium bromide (NaBr) in phenyl-butylammonium (PBA)-containing mixed-halide Q-2D perovskites for a blue perovskite light-emitting diode (PeLED). The incorporation of alkali metal contributes to the nucleation and growth of Q-2D perovskites into graded distribution of domains with different layer number . The study of excitation dynamics by transient absorption (TA) spectroscopy confirms that NaBr induces more Q-2D perovskite phases with small n number, providing a graded energy cascade pathway to facilitate more efficient energy transfer processes. In addition, the nonradiative recombination within the Q-2D perovskites is significantly suppressed upon Na+ incorporation, as validated by the trap density estimation. Consequently, the optimized blue PeLEDs manifest a peak external quantum efficiency (EQE) of 7.0% emitting at 486 nm with a maximum luminance of 1699 cd m(-2). It is anticipated that these findings will improve the understanding of alkali-metal-assisted optimization of Q-2D perovskites and pave the way toward high-performance blue PeLEDs.
URI http://hdl.handle.net/20.500.11897/643389
DOI 10.1002/advs.202200393
Indexed SCI(E)
Appears in Collections: 新材料学院

Files in This Work
There are no files associated with this item.

Web of Science®


0

Checked on Last Week

Scopus®



Checked on Current Time

百度学术™


0

Checked on Current Time

Google Scholar™





License: See PKU IR operational policies.