Title Batch synthesis of transfer-free graphene with wafer-scale uniformity
Authors Jiang, Bei
Zhao, Qiyue
Zhang, Zhepeng
Liu, Bingzhi
Shan, Jingyuan
Zhao, Liang
Rummeli, Mark H.
Gao, Xuan
Zhang, Yanfeng
Yu, Tongjun
Sun, Jingyu
Liu, Zhongfan
Affiliation Peking Univ, Ctr Nanochem CNC, Beijing Sci & Engn Ctr Nanocarbons, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Peking Univ, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop P, Beijing 100871, Peoples R China
Soochow Univ, Coll Energy, Soochow Inst Energy & Mat Innovat SIEMIS, Key Lab Adv Carbon Mat & Wearable Energy Technol, Suzhou 215006, Peoples R China
BGI, Beijing 100095, Peoples R China
Keywords CHEMICAL-VAPOR-DEPOSITION
FEW-LAYER GRAPHENE
LARGE-AREA
GROWTH
FILMS
OXIDE
EXFOLIATION
GLASS
Issue Date Apr-2020
Publisher NANO RESEARCH
Abstract Scalable synthesis of transfer-free graphene over insulators offers exciting opportunity for next-generation electronics and optoelectronics. However, rational design of synthetic protocols to harvest wafer-scale production of directly grown graphene still remains a daunting challenge. Herein we explore a batch synthesis of large-area graphene with wafer-scale uniformity by virtue of direct chemical vapor deposition (CVD) on quartz. Such a controllable CVD approach allows to synthesize 30 pieces of 4-inch graphene wafers in one batch, affording a low fluctuation of optical and electrical properties. Computational fluid dynamics simulations reveal the mechanism of uniform growth, indicating thermal field and confined flow field play leading roles in attaining the batch uniformity. The resulting wafer-scale graphene enables the direct utilization as key components in optical elements. Our method is applicable to other types of insulating substrates (e.g., sapphire, SiO2/Si, Si3N4), which may open a new avenue for direct manufacture of graphene wafers in an economic fashion.
URI http://hdl.handle.net/20.500.11897/606623
ISSN 1998-0124
DOI 10.1007/s12274-020-2771-3
Indexed SCI(E)
Scopus
EI
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物理学院
人工微结构和介观物理国家重点实验室

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