Title Preparation and Characterization of Flexible Smart Glycol/Polyvinylpyrrolidone/Nano-Al2O3 Phase Change Fibers
Authors Zhang, Xiaoguang
Wu, Bogang
Chen, Guo
Xu, Yunfei
Shi, Tengteng
Huang, Zhaohui
Liu, Yangai
Fang, Minghao
Wu, Xiaowen
Min, Xin
Affiliation China Univ Geosci, Sch Mat Sci & Technol, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Natl Lab Mineral Mat, Beijing 100083, Peoples R China
Peking Univ, Beijing Innovat Ctr Engn Sci & Adv Technol, Beijing Key Lab Magnetoelect Mat & Devices, Dept Mat Sci & Engn,Coll Engn, Beijing 100871, Peoples R China
Keywords THERMAL-ENERGY-STORAGE
CONDUCTIVITY ENHANCEMENT
NANOFIBER COMPOSITES
POLYETHYLENE-GLYCOL
CARBON-FIBER
PERFORMANCE
PCM
HEAT
GRAPHENE
NANOCOMPOSITE
Issue Date 7-Jan-2021
Publisher ENERGY & FUELS
Abstract The development of flexible smart phase change fibers has been limited because of the low production rate and safety concerns of electrospinning. Therefore, a novel centrifugal spinning technology, which is a safe and large-scale fabrication approach, is employed to extrude flexible smart phase change fibers using polyethylene glycol (PEG) and polyvinylpyrrolidone (PVP). Nano-Al2O3 was employed to enhance the thermal conductivity of flexible smart PEG/PVP phase change fibers. The flexible smart PEG/PVP/Nano-Al2O3 phase change fibers have a clear cylindrical fiber shape, no cross-linking, and uniform fiber axial distribution. The interactions in flexible smart PEG/PVP/Nano-Al2O3 phase change fibers involve physical loading in PEG, PVP, and Nano-Al2O3. The flexible smart PEG/PVP/Nano-Al2O3 9.0% phase change fibers have a latent heat of 50.7 J/g at the melting point of 46.7 degrees C. The flexible fibers have ideal thermal stability and thermal cycle stability, and the shape of flexible fibers remained stable during the phase-change process. The thermal conductivity of flexible smart PEG/PVP/Nano-Al2O3 9.0% phase change fibers was 3.05 times greater than that of PEG/PVP fibers. The flexible smart fibers are promising for applications in the field of thermal insulation.
URI http://hdl.handle.net/20.500.11897/604281
ISSN 0887-0624
DOI 10.1021/acs.energyfuels.0c03370
Indexed SCI(E)
Appears in Collections: 工学院

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