| Title | Collective and individual impacts of the cascade doping of alkali cations in perovskite single crystals |
| Authors | Zhang, Yu Huang, Yuan Wang, Xiaoge Sun, Junliang Si, Rui Zhou, Huanping |
| Affiliation | Peking Univ, Beijing Key Lab Theory & Technol Adv Battery Mat, Key Lab Polymer Chem & Phys, Minist Educ,BIC ESAT,Dept Mat Sci & Engn,Coll Eng, Beijing 100871, Peoples R China Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China |
| Keywords | SOLAR-CELLS HALIDE PEROVSKITES HIGH-PERFORMANCE |
| Issue Date | 21-Nov-2020 |
| Publisher | JOURNAL OF MATERIALS CHEMISTRY C |
| Abstract | Alkali ion (Cs+, Rb+ and K+) incorporated hybrid perovskite polycrystalline films have shown great potential for obtaining highly efficient and stable perovskite solar cells. A study on the intrinsic influence of different alkali ions on perovskites is urgently needed to gain insights into the optoelectronic performance improvement. Single crystals with fewer defects can be ideal candidates for the study of intrinsic properties. Herein, for the first time, we prepared a series of perovskite (FA(0.85)MA(0.15)PbI(2.55)Br(0.45)) single crystals with Cs+, Rb+, and K+ cascade doping using the "inverse temperature crystallization" method and systematically characterized their structure and optoelectronic properties, as well as phase, humidity and thermal stability. Our work highlights the structure-property relationship, that is, diversified A-site occupation (especially the FAMACsRb system) can significantly promote the carrier transport behavior of perovskites, as well as achieving better thermal and humidity stability, while K+ doping degrades the intrinsic properties of perovskites, which is probably due to the interstitial occupation of K+. These findings deepen the understanding of the influence of alkali ion doping on the intrinsic properties of perovskite materials, which will provide an exemplary paradigm for further exploration. |
| URI | http://hdl.handle.net/20.500.11897/599469 |
| ISSN | 2050-7526 |
| DOI | 10.1039/d0tc03085f |
| Indexed | SCI(E) |
| Appears in Collections: | 工学院 高分子化学与物理教育部重点实验室 先进电池材料料理论与技术北京市重点实验室 å å¦ä¸ å å å·¥ç¨ å¦é ¢ |
