Title Application of moisture-induced discoloration material Nickel(II) iodide in humidity detection
Authors Zhang, Yong
Ren, Jianxu
Wu, Yiwei
Zhong, Xiangli
Luo, Tao
Cao, Juexian
Yin, Mengqi
Huang, Mingpeng
Zhang, Zhiyong
Affiliation Xiangtan Univ, Sch Phys & Optoelect, Xiangtan 411105, Peoples R China
Xiangtan Univ, Hunan Inst Adv Sensing & Informat Technol, Xiangtan 411105, Peoples R China
Peking Univ, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China
Peking Univ, Dept Elect, Beijing 100871, Peoples R China
Xiangtan Univ, Sch Mat Sci & Engn, Key Lab Low Dimens Mat & Applicat Technol, Minist Educ, Xiangtan 411105, Peoples R China
Keywords GRAPHENE OXIDE
SENSOR
SURFACE
PAPER
Issue Date 15-Apr-2020
Publisher SENSORS AND ACTUATORS B-CHEMICAL
Abstract Ultra-low humidity detection is significant in some important industrial fields, such as integrated circuit manufacturing, chip packaging. However, the traditional ionic-type humidity sensor is not competent for the detection of ultra-low humidity, but can only realize the detection of medium humidity to high humidity. Here, moisture-induced discoloration material Nickel(II) iodide (NiI2) is found to be highly sensitive to moisture, and both its electrical properties and color will change with environmental humidity variation. Especially, NiI2 exhibits the largest impedance change to date in the ultra-low humidity range compared with state of the art. The impedance variation is up to 2 orders of magnitude in the range of 0.4 %-11 % RH, which means that NiI2 can realize the detection of ultra-low humidity. The excellent performance of NiI2 in ultra-low humidity is attributed to the material transition characteristics susceptible to humidity rather than the traditional surface mechanism of water adsorption. Moreover, combining the reversible black-to-transparency moisture-induced discoloration behavior with humidity sensing properties, a flexible wristband based on NiI2 is developed to realize the dual-mode detection of wide range environmental humidity. These results demonstrate that NiI2 has great application prospects in professional ultra-low humidity detection and wearable humidity detection equipment.
URI http://hdl.handle.net/20.500.11897/586155
DOI 10.1016/j.snb.2020.127769
Indexed SCI(E)
Scopus
EI
Appears in Collections: 纳米器件物理与化学教育部重点实验室
信息科学技术学院

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