Title K-0.36(H2O)(y)WS2: a new layered compound for reversible hydrated potassium ion intercalation in aqueous electrolyte
Authors Mao, Yuanlv
Xie, Miao
Zhao, Wei
Yuan, Kaidi
Fang, Yuqiang
Huang, Fuqiang
Affiliation Chinese Acad Sci, State Key Lab High Performance Ceram & Superne Mi, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R China
ShanghaiTech Univ, Shanghai 201210, Peoples R China
Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Issue Date 2019
Publisher RSC ADVANCES
Abstract This work reports the synthesis of a new quasi two-dimensional layered compound, K-0.36(H2O)(y)WS2, for aqueous potassium ion storage. Its crystal structure determined by single crystal X-ray diffraction is composed of WS2 layers and disordered hydrated K+ stacking along the c direction alternately. Due to the large interlayer spacing and high conductivity, K-0.36(H2O)(y)WS2 is demonstrated to be a stable host for reversible intercalation and de-intercalation of hydrated K+ in K2SO4 aqueous solution.
URI http://hdl.handle.net/20.500.11897/553411
DOI 10.1039/c9ra07718a
Indexed SCI(E)
EI
Appears in Collections: å å¦ä¸ å å å·¥ç¨ å¦é ¢
稀土材料化学与应用国家重点实验室

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