Title | K-0.36(H2O)(y)WS2: a new layered compound for reversible hydrated potassium ion intercalation in aqueous electrolyte |
Authors | Mao, Yuanlv Xie, Miao Zhao, Wei Yuan, Kaidi Fang, Yuqiang Huang, Fuqiang |
Affiliation | Chinese Acad Sci, State Key Lab High Performance Ceram & Superne Mi, Shanghai Inst Ceram, Shanghai 200050, Peoples R China Univ Chinese Acad Sci, Beijing 100049, Peoples R China ShanghaiTech Univ, Shanghai 201210, Peoples R China Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
Issue Date | 2019 |
Publisher | RSC ADVANCES |
Abstract | This work reports the synthesis of a new quasi two-dimensional layered compound, K-0.36(H2O)(y)WS2, for aqueous potassium ion storage. Its crystal structure determined by single crystal X-ray diffraction is composed of WS2 layers and disordered hydrated K+ stacking along the c direction alternately. Due to the large interlayer spacing and high conductivity, K-0.36(H2O)(y)WS2 is demonstrated to be a stable host for reversible intercalation and de-intercalation of hydrated K+ in K2SO4 aqueous solution. |
URI | http://hdl.handle.net/20.500.11897/553411 |
DOI | 10.1039/c9ra07718a |
Indexed | SCI(E) EI |
Appears in Collections: | å å¦ä¸ å å å·¥ç¨ å¦é ¢ 稀土材料化学与应用国家重点实验室 |