Title Applications of 2D MXenes in energy conversion and storage systems
Authors Pang, Jinbo
Mendes, Rafael G.
Bachmatiuk, Alicja
Zhao, Liang
Ta, Huy Q.
Gemming, Thomas
Liu, Hong
Liu, Zhongfan
Rummeli, Mark H.
Affiliation Leibniz Inst Solid State & Mat Res Dresden IFW Dr, Helmholtzstr 20, D-01069 Dresden, Germany
Univ Jinan, iAIR, Jinan 250022, Shandong, Peoples R China
Soochow Univ, Sch Energy, Soochow Inst Energy & Mat Innovat SIEMIS, Optoelect & Energy, Suzhou 215006, Peoples R China
Soochow Univ, Sch Energy, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215006, Peoples R China
Soochow Univ, Sch Energy, Key Lab Adv Carbon Mat & Wearable Energy Technol, Suzhou 215006, Peoples R China
Polish Acad Sci CMPW PAN, Ctr Polymer & Carbon Mat, Ul M Curie Sklodowskiej 34, PL-41819 Zabrze, Poland
Shandong Univ, Ctr Bio & Micro Nano Funct Mat, State Key Lab Crystal Mat, 27 Shandanan Rd, Jinan 250100, Shandong, Peoples R China
Peking Univ, Coll Chem & Mol Engn, Beijing Sci & Engn Ctr Nanocarbons, Ctr Nanochem CNC, Beijing 100871, Peoples R China
Issue Date 2019
Publisher CHEMICAL SOCIETY REVIEWS
Abstract Transition metal carbides and nitrides (MXenes), a family of two-dimensional (2D) inorganic compounds, are materials composed of a few atomic layers of transition metal carbides, nitrides, or carbonitrides. Ti3C2, the first 2D layered MXene, was isolated in 2011. This material, which is a layered bulk material analogous to graphite, was derived from its 3D phase, Ti3AlC2 MAX. Since then, material scientists have either determined or predicted the stable phases of >200 different MXenes based on combinations of various transition metals such as Ti, Mo, V, Cr, and their alloys with C and N. Extensive experimental and theoretical studies have shown their exciting potential for energy conversion and electrochemical storage. To this end, we comprehensively summarize the current advances in MXene research. We begin by reviewing the structure types and morphologies and their fabrication routes. The review then discusses the mechanical, electrical, optical, and electrochemical properties of MXenes. The focus then turns to their exciting potential in energy storage and conversion. Energy storage applications include electrodes in rechargeable lithium-and sodium-ion batteries, lithium-sulfur batteries, and supercapacitors. In terms of energy conversion, photocatalytic fuel production, such as hydrogen evolution from water splitting, and carbon dioxide reduction are presented. The potential of MXenes for the photocatalytic degradation of organic pollutants in water, such as dye waste, is also addressed, along with their promise as catalysts for ammonium synthesis from nitrogen. Finally, their application potential is summarized.
URI http://hdl.handle.net/20.500.11897/551561
ISSN 0306-0012
DOI 10.1039/c8cs00324f
Indexed SCI(E)
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