Title | Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(ii) complex |
Authors | Huang, Zhe Tan, Gengwen Chen, Chao Zhang, Wen-Xiong Wang, Xinping Xi, Zhenfeng |
Affiliation | Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210023, Jiangsu, Peoples R China |
Issue Date | 2019 |
Publisher | CHEMICAL COMMUNICATIONS |
Abstract | Selective reduction of 1,5-diazacyclooctatetraenes with potassium or a Co(I) complex was achieved to provide the first structurally well-defined aromatic 1,5-diazacyclooctatetraenyl dianion or a novel dinuclear Co(II) complex bridged by a bipyrrolinyl dianion, respectively. |
URI | http://hdl.handle.net/20.500.11897/543802 |
ISSN | 1359-7345 |
DOI | 10.1039/c9cc00075e |
Indexed | IC SCI(E) EI |
Appears in Collections: | å å¦ä¸ å å å·¥ç¨ å¦é ¢ 生物有机与分子工程教育部重点实验室 |