| Title | Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides |
| Authors | Yu, Weijie Chen, Long Tao, Jiasi Wang, Tao Fu, Junkai |
| Affiliation | Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China Jiangxi Normal Univ, Key Lab Chem Biol, Nanchang 330022, Jiangxi, Peoples R China Northeast Normal Univ, Dept Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Jilin, Peoples R China Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Key Lab Chem Genom, Shenzhen 518055, Peoples R China |
| Issue Date | 2019 |
| Publisher | CHEMICAL COMMUNICATIONS |
| Abstract | A novel reductive cross- coupling of aryl vinyl halides and unactivated tertiary alkyl bromides has been realized via photoredox/ nickel dual catalysis to produce vinyl arene derivatives bearing all- carbon quaternary centers with excellent E- selectivity. A stoichiometric metal reductant could be avoided by employing commercially available N, N, N0, N0- tetramethylethylenediamine ( TMEDA) as the terminal reductant. |
| URI | http://hdl.handle.net/20.500.11897/543531 |
| ISSN | 1359-7345 |
| DOI | 10.1039/c9cc00768g |
| Indexed | CCR IC SCI(E) EI |
| Appears in Collections: | 深圳研究生院待认领 |
