| Title | Electropolymerization Porous Aromatic Framework Film As a Hole-Transport Layer for Inverted Perovskite Solar Cells with Superior Stability |
| Authors | Wang, Yudi Zhang, Shuhao Wu, Jionghua Liu, Kuan Li, Dongmei Meng, Qingbo Zhu, Guangshan |
| Affiliation | Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China. Northeast Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China. Chinese Acad Sci, Inst Phys, Beijing Key Lab New Energy Mat & Devices, Key Lab Renewable Energy CAS, Beijing 100190, Peoples R China. Peking Univ, Minist Educ, Coll Engn, Dept Mat Sci & Engn,Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China. Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China. Zhu, GS (reprint author), Northeast Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China. |
| Keywords | porous aromatic framework electropolymerization perovskite solar cells hole transport long-term stability MICROPOROUS POLYMER NETWORKS THIN-FILMS CONJUGATED POLYMERS ORGANIC POLYMER EFFICIENT DESIGN DEPOSITION OXIDE CU2O |
| Issue Date | 2017 |
| Publisher | ACS APPLIED MATERIALS & INTERFACES |
| Citation | ACS APPLIED MATERIALS & INTERFACES. 2017, 9(50), 43688-43695. |
| Abstract | PAF-86 film is electropolymerized (EP) by targeted monomer M1 tethered bifunctional carbozolyl moieties which not only serve in electron donation but also provide effective electrochemical (EC) active sites. The resulting PAF-86 film possesses a fairly compact surface, remarkable stability, efficient hole extraction capacity, and hole-transporting materials (HTMs) for inverted heterojunction perovskite solar cells (PSCs). Likewise, our investigation shows that PAF-86 film based perovskite solar cells (PSCs) retained about 80% power conversion efficiency (PCE) without encapsulation in air, and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) based PSCs devices reduce to 4% under the same conditions. More impressively, the electropolymerization approach is convenient, controlled, and operated at ambient conditions which elude post heat-treatments and are appropriate for industrial application. |
| URI | http://hdl.handle.net/20.500.11897/500339 |
| ISSN | 1944-8244 |
| DOI | 10.1021/acsami.7b14073 |
| Indexed | SCI(E) EI PubMed |
| Appears in Collections: | 工学院 高分子化学与物理教育部重点实验室 |
