TitleA Facile All-Solution-Processed Surface with High Water Contact Angle and High Water Adhesive Force
AuthorsChen, Mei
Hu, Wei
Liang, Xiao
Zou, Cheng
Li, Fasheng
Zhang, Lanying
Chen, Feiwu
Yang, Huai
AffiliationPeking Univ, Dept Mat Sci & Engn, Coll Engn, Beijing 100871, Peoples R China.
Peking Univ, Key Lab Polymer Chem & Phys, Minist Educ, Beijing 100871, Peoples R China.
Univ Sci & Technol Beijing, Dept Chem, Beijing 100083, Peoples R China.
Dalian Med Univ, Dept Chem, Dalian 116044, Peoples R China.
Peking Univ, Dept Mat Sci & Engn, Coll Engn, Beijing 100871, Peoples R China.
Zhang, LY
Yang, HA (reprint author), Peking Univ, Key Lab Polymer Chem & Phys, Minist Educ, Beijing 100871, Peoples R China.
Keywordspolymerization-induced phase separation
epoxy microspheres
hierarchical structures
high apparent contact angle
high water adhesive force
DISPERSED LIQUID-CRYSTALS
INDUCED PHASE-SEPARATION
SOLUTION-IMMERSION PROCESS
SUPERHYDROPHOBIC SURFACES
ELECTROOPTICAL PROPERTIES
OXIDE SURFACES
SINGLE-PHASE
POLYMER
FILMS
FABRICATION
Issue Date2017
PublisherACS APPLIED MATERIALS & INTERFACES
CitationACS APPLIED MATERIALS & INTERFACES.2017,9(27),23246-23254.
AbstractA series of sticky superhydrophobicity surfaces with high water contact angle and high water adhesive force is facilely prepared via an all-solution-processed method based on polymerization-induced phase separation between liquid crystals (LCs) and epoxy resin, which produces layers of epoxy microspheres (EMSs) with nanofolds on the surface of a substrate. The morphologies and size distributions of EMSs are confirmed by scanning electron microscopy. Results reveal that the obtained EMS coated-surface exhibits high apparent contact angle of 152.0 degrees and high water adhesive force up to 117.6 mu N. By varying the composition of the sample or preparing conditions, the sizes of the produced EMSs can be artificially regulated and, thus, control the wetting properties and water adhesive behaviors. Also, the sticky superhydrophobic surface exhibits excellent chemical stability, as well as long-term durability. Water droplet transportation experiments further prove that the as-made surface can be effectively used as a mechanical hand for water transportation applications. Based on this, it is believed that the simple method proposed in this paper will pave a new way for producing a sticky superhydrophobic surface and obtain a wide range of use.
URIhttp://hdl.handle.net/20.500.11897/472166
ISSN1944-8244
DOI10.1021/acsami.7b07429
IndexedSCI(E)
Appears in Collections:工学院
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