Title Controlled growth of large-area anisotropic ReS2 atomic layer and its photodetector application
Authors Li, Xiaobo
Cui, Fangfang
Feng, Qingliang
Wang, Gang
Xu, Xiaosa
Wu, Juanxia
Mao, Nannan
Liang, Xing
Zhang, Zhongyue
Zhang, Jin
Xu, Hua
Affiliation Shaanxi Normal Univ, Key Lab Appl Surface & Colloid Chem, Shaanxi Key Lab Adv Energy Devices,Minist Educ, Shaanxi Engn Lab Adv Energy Technol Sch Mat Sci &, Xian 710119, Peoples R China.
Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Key Lab Phys & Chem Nanodevices,Ctr Nanochem, Beijing Natl Lab Mol Sci,Coll Chem & Mol Engn, Beijing 100871, Peoples R China.
Shaanxi Normal Univ, Sch Phys & Informat Technol, Xian 710119, Peoples R China.
Keywords CHEMICAL-VAPOR-DEPOSITION
FIELD-EFFECT TRANSISTORS
RHENIUM DISULFIDE RES2
FEW-LAYER
RAMAN-SPECTROSCOPY
INPLANE ANISOTROPY
HIGH RESPONSIVITY
BLACK PHOSPHORUS
MONOLAYER
SEMICONDUCTOR
Issue Date 2016
Publisher NANOSCALE
Citation NANOSCALE.2016,8(45),18956-18962.
Abstract As an anisotropic 2D layered material, rhenium disulfide (ReS2) has attracted much attention because of its unusual properties and promising applications in electronic and optoelectronic devices. However, the low lattice symmetry and interlayer decoupling of ReS2 make asymmetric growth and out-of-plane growth occur quite easily; therefore, thick flake, dendritic and flower-like structures of ReS2 have mostly been obtained previously. Here, we report on an approach based on space-confined epitaxial growth for the controlled synthesis of ReS2 films. Using this approach, large-area and high-quality ReS2 films with uniform monolayer thickness can grow on a mica substrate. Furthermore, the weak van der Waals interaction between the surface of mica and ReS2 clusters, which favors surface-confined growth while avoiding out-of-plane growth, is critical for growing ReS2 with uniform monolayer thickness. The morphological evolution of ReS2 with the growth temperature reveals that asymmetric growth can be suppressed at relatively low temperatures. A ReS2 field-effect transistor displayed a current on/off ratio of 1(0)6 and an electron mobility of up to 40 cm(2) V-1 s(-1), with outstanding photoresponsivity of 12 A W-1. This work not only promotes the large-scale employment of ReS2 in high-performance optoelectronic devices, but also provides a means of controlling the unusual growth behavior of low-lattice-symmetry 2D layered materials.
URI http://hdl.handle.net/20.500.11897/457154
ISSN 2040-3364
DOI 10.1039/c6nr07233j
Indexed SCI(E)
PubMed
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