TitlePreparation and characterization of a porphyrin self-assembled monolayer with a controlled orientation on gold
AuthorsZhang, Zhijun
Hou, Shifeng
Zhu, Zihua
Liu, Zhongfan
AffiliationCtr. for Nanoscale Sci. and Technol., Coll. of Chem. and Molec. Eng., Peking University, Beijing 100871, China
Res. Center for Materials Science, Nagoya University, Chikusa, Nagoya 464, Japan
Issue Date2000
Publisherlangmuir
CitationLangmuir.2000,16,(2),537-540.
AbstractA porphyrin-incorporated self-assembled monolayer (SAM) on gold, in which the macroplane of the porphyrin molecule assumes a nearly fiat orientation with respect to the surface of the Au substrate, was prepared by formation of a 4-pyridinethiol SAM on gold followed by axial ligation of metalloporphyrin (CoTPP) to it. The porphyrin SAM was characterized by surface-enhanced Raman scattering (SERS) and electrochemical techniques.
URIhttp://hdl.handle.net/20.500.11897/409605
ISSN07437463
DOI10.1021/la990570g
IndexedEI
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