Title | Preparation and characterization of a porphyrin self-assembled monolayer with a controlled orientation on gold |
Authors | Zhang, Zhijun Hou, Shifeng Zhu, Zihua Liu, Zhongfan |
Affiliation | Ctr. for Nanoscale Sci. and Technol., Coll. of Chem. and Molec. Eng., Peking University, Beijing 100871, China Res. Center for Materials Science, Nagoya University, Chikusa, Nagoya 464, Japan |
Issue Date | 2000 |
Publisher | langmuir |
Citation | Langmuir.2000,16,(2),537-540. |
Abstract | A porphyrin-incorporated self-assembled monolayer (SAM) on gold, in which the macroplane of the porphyrin molecule assumes a nearly fiat orientation with respect to the surface of the Au substrate, was prepared by formation of a 4-pyridinethiol SAM on gold followed by axial ligation of metalloporphyrin (CoTPP) to it. The porphyrin SAM was characterized by surface-enhanced Raman scattering (SERS) and electrochemical techniques. |
URI | http://hdl.handle.net/20.500.11897/409605 |
ISSN | 07437463 |
DOI | 10.1021/la990570g |
Indexed | EI |
Appears in Collections: | 待认领 |