Title | PREPARATION AND STRUCTURAL STUDY OF 110K SUPERCONDUCTING PHASE IN B1 (Pb)-Sr-Ca-Cu-0 SYSTEM |
Authors | Lu Weijing Zhang Yufen Zheng Xiangmiao Wei Chengqian Wei Zhaoqing He Jun |
Affiliation | Peking Univ, Inst Phys Chem, Lab Appl Phys Chem, Beijing, Peoples R China. Guangxi Univ, Dept Chem, Nanning, Peoples R China. |
Issue Date | 1989 |
Publisher | 物理化学学报 |
Citation | ACTA PHYSICO-CHIMICA SINICA.1989,5,(2),129-134. |
Abstract | The stable superconducting phase with T-c 110 k has been prepared in samples of nominal composition (Big-x Pb-x) Sr-2 Ca-2 Cu-3 O-r and (Big-x Pb-x)Sr-2 Ca-2 Cu-2 O-r with T-c 106. K-3 has been determined in the sample of nominal compositions (Bi1-8Pb0.2)Sr-2 Ca-2 Cu-5 O-y. It is a nine deckter perovskite arrangement by incorporating two extra layer CaCuO2, space group D1/2h - Pmmm was assigned. Adding Pb is in Bi site, and atomic radius and atomic valence in Bi site was modified, so that it is able to stabilize crystal structure and progress superconducting properties. |
URI | http://hdl.handle.net/20.500.11897/390320 |
ISSN | 1000-6818 |
DOI | 10.3866/PKU.WHXB19890201 |
Indexed | SCI(E) 中国科学引文数据库(CSCD) |
Appears in Collections: | 待认领 |