Title PREPARATION AND STRUCTURAL STUDY OF 110K SUPERCONDUCTING PHASE IN B1 (Pb)-Sr-Ca-Cu-0 SYSTEM
Authors Lu Weijing
Zhang Yufen
Zheng Xiangmiao
Wei Chengqian
Wei Zhaoqing
He Jun
Affiliation Peking Univ, Inst Phys Chem, Lab Appl Phys Chem, Beijing, Peoples R China.
Guangxi Univ, Dept Chem, Nanning, Peoples R China.
Issue Date 1989
Publisher 物理化学学报
Citation ACTA PHYSICO-CHIMICA SINICA.1989,5,(2),129-134.
Abstract The stable superconducting phase with T-c 110 k has been prepared in samples of nominal composition (Big-x Pb-x) Sr-2 Ca-2 Cu-3 O-r and (Big-x Pb-x)Sr-2 Ca-2 Cu-2 O-r with T-c 106. K-3 has been determined in the sample of nominal compositions (Bi1-8Pb0.2)Sr-2 Ca-2 Cu-5 O-y. It is a nine deckter perovskite arrangement by incorporating two extra layer CaCuO2, space group D1/2h - Pmmm was assigned. Adding Pb is in Bi site, and atomic radius and atomic valence in Bi site was modified, so that it is able to stabilize crystal structure and progress superconducting properties.
URI http://hdl.handle.net/20.500.11897/390320
ISSN 1000-6818
DOI 10.3866/PKU.WHXB19890201
Indexed SCI(E)
中国科学引文数据库(CSCD)
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