| Title | Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates |
| Authors | Zhou, Lei Liu, Yizhou Zhang, Yan Wang, Jianbo |
| Affiliation | Peking Univ, Coll Chem, BNLMS, Key Lab Bioorgan Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China. |
| Keywords | alkyne carbene O-H insertion cyclization diazo compounds gold catalysis 1H-isochromene ALPHA-DIAZOCARBONYL COMPOUNDS CARBENE-TRANSFER-REACTIONS CYCLIC ALKENYL ETHERS ORGANIC-SYNTHESIS TANDEM CATALYSIS TERMINAL ALKYNES GOLD COMPLEXES LEWIS-ACID CYCLIZATION ALKYNYLBENZALDEHYDES |
| Issue Date | 2011 |
| Publisher | beilstein journal of organic chemistry |
| Citation | BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY.2011,7,631-637. |
| Abstract | The gold(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates provides 1H-isochromene derivatives in good yields. The reaction follows a catalytic sequence of gold carbene formation/water O-H insertion/alcohol-alkyne cyclization. The gold(I) complex is the only catalyst in each of these steps. |
| URI | http://hdl.handle.net/20.500.11897/343701 |
| ISSN | 1860-5397 |
| DOI | 10.3762/bjoc.7.74 |
| Indexed | SCI(E) PubMed |
| Appears in Collections: | å å¦ä¸ å å å·¥ç¨ å¦é ¢ 生物有机与分子工程教育部重点实验室 |
