Title Helicity-dependent single-walled carbon nanotube alignment on graphite for helical angle and handedness recognition
Authors Chen, Yabin
Shen, Ziyong
Xu, Ziwei
Hu, Yue
Xu, Haitao
Wang, Sheng
Guo, Xiaolei
Zhang, Yanfeng
Peng, Lianmao
Ding, Feng
Liu, Zhongfan
Zhang, Jin
Affiliation Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn,Ctr Nanochem, Beijing Natl Lab Mol Sci,Key Lab Phys & Chem Nano, Beijing 100871, Peoples R China.
Peking Univ, Dept Elect, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China.
Hong Kong Polytech Univ, Inst Text & Clothing, Hong Kong, Hong Kong, Peoples R China.
Beijing Computat Sci Res Ctr, Beijing 100084, Peoples R China.
Keywords ORIENTED GROWTH
GRAPHENE
TRANSITIONS
ELECTRONICS
Issue Date 2013
Publisher nature communications
Citation NATURE COMMUNICATIONS.2013,4.
Abstract Aligned single-walled carbon nanotube arrays provide a great potential for the carbon-based nanodevices and circuit integration. Aligning single-walled carbon nanotubes with selected helicities and identifying their helical structures remain a daunting issue. The widely used gas-directed and surface-directed growth modes generally suffer the drawbacks of mixed and unknown helicities of the aligned single-walled carbon nanotubes. Here we develop a rational approach to anchor the single-walled carbon nanotubes on graphite surfaces, on which the orientation of each single-walled carbon nanotube sensitively depends on its helical angle and handedness. This approach can be exploited to conveniently measure both the helical angle and handedness of the single-walled carbon nanotube simultaneously at a low cost. In addition, by combining with the resonant Raman spectroscopy, the (n,m) index of anchored single-walled carbon nanotube can be further determined from the (d,theta) plot, and the assigned (n, m) values by this approach are validated by both the electronic transition energy E-ii measurement and nanodevice application.
URI http://hdl.handle.net/20.500.11897/313029
ISSN 2041-1723
DOI 10.1038/ncomms3205
Indexed SCI(E)
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信息科学技术学院
纳米器件物理与化学教育部重点实验室

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