| Title | Synthesis and electrochemical characterization of Li1.05RExCryMn2-x-yO4 spinel as cathode material for rechargeable Li-battery |
| Authors | Xie, Yanting Yang, Rudong Yan, Lan Qi, Lu Dai, Kehua He, Ping |
| Affiliation | Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China. Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China. |
| Keywords | secondary Li-ion battery co-doped lithium manganese spinels cyclic voltammetry LICRYMN2-YO4 0-LESS-THAN-OR-EQUAL-TO-Y-LESS-THAN-OR-EQUAL-TO-1 COMPOUNDS LITHIUM BATTERIES SUPERFICIAL PROCESSES CR CONTENT LIMN2O4 BEHAVIOR PHASE CELLS BULK FE |
| Issue Date | 2007 |
| Publisher | 电源杂志 |
| Citation | JOURNAL OF POWER SOURCES.2007,168,(1,SI),272-277. |
| Abstract | The spinel phases of Li1.05RExCryMn2-x-yO4 (RE= Sc, Ce, Pr, Tb; 0 <= x <= 0.05; 0 <= y <= 0.1) were prepared by a soft chemical method. The structural and electrochemical properties of Li1.05RExCryMn2-x-yO4 were investigated by X-ray diffraction (XRD), Transmission electron microscopy (TEM) and charge-discharge experiments. Rare earth element-Sc and transition metal-Cr as co-substituents stabilize the spinel framework and improve charge-discharge performance. For Li1.05Sc0.01Cr0.03Mn1.96O4, the capacity of the cell maintained 95% of the initial capacity at the 80th cycle. The rare earth elements of the variable valent metals such as Ce3+/4+, Pr3+/4+, Tb3+/4+ with transition metal Cr3+ as co-substituent do not stable framework of spinel or improve the cycling performance. Cyclic voltammetry CV) were measured to provide clues for the improved cycling performance of cathode electrodes. (C) 2007 Published by Elsevier B.V. |
| URI | http://hdl.handle.net/20.500.11897/250911 |
| ISSN | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2007.01.019 |
| Indexed | SCI(E) EI |
| Appears in Collections: | å å¦ä¸ å å å·¥ç¨ å¦é ¢ |
