Title Analysis of surface effect on luminescent properties of Eu3+ in YVO4 nanocrystals
Authors Peng, Hongshang
Huang, Shihua
Sun, Lingdong
Yan, Chunhua
Affiliation Beijing Jiaotong Univ, Minist Educ, Key Lab Luminescence & Opt Informat, Beijing 100044, Peoples R China.
Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China.
Keywords surface sate
nanocrystal
electrostatic point charge model
luminescence
CRYSTAL-FIELD ANALYSIS
RARE-EARTH IONS
OPTICAL-SPECTRA
ENERGY-LEVELS
KRAMERS IONS
C2 SITES
Y2O3
Issue Date 2007
Publisher physics letters a
Citation PHYSICS LETTERS A.2007,367,(3),211-214.
Abstract this Letter, F-7(2) crystal field (CF) levels of surface Eu3+ in YVO4 nanocrystals are calculated employing a refined electrostatic point charge model. where surface states are simulated by point charges. Based on the theoretical F-7(2) CF levels, emission spectra Of YVO4: Eu3+ nanocrystals are assianed to Eu3+ under different local environments. and relaxation of selection rules by surface effect is discussed. (c) 2007 Elsevier B.V. All rights reserved.
URI http://hdl.handle.net/20.500.11897/250013
ISSN 0375-9601
DOI 10.1016/j.physleta.2007.03.030
Indexed SCI(E)
Appears in Collections: 稀土材料化学与应用国家重点实验室

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