| Title | Long-term performance of polyetheretherketone-based polymer electrolyte membrane in fuel cells at 95 A degrees C |
| Authors | Chen, Jinhua Zhai, Maolin Asano, Masaharu Huang, Ling Maekawa, Yasunari |
| Affiliation | JAEA, Environm & Ind Mat Res Div, Takasaki, Gumma 3701292, Japan. Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China. JAEA, Environm & Ind Mat Res Div, 1233 Watanuki Machi, Takasaki, Gumma 3701292, Japan. |
| Keywords | PROTON-EXCHANGE MEMBRANES HIGH-TEMPERATURE ETFE FILMS COMPOSITE MEMBRANES GRAFTING METHOD RADIATION DEGRADATION DURABILITY PEFC MONOMERS |
| Issue Date | 2009 |
| Publisher | journal of materials science |
| Citation | JOURNAL OF MATERIALS SCIENCE.2009,44,(14),3674-3681. |
| Abstract | A poly(styrenesulfonic acid)-grafted polyetheretherketone (ssPEEK) polymer electrolyte membrane was developed by radiation grafting of ethyl styrenesulfonate (ETSS) onto PEEK film and subsequent hydrolysis. The long-term durability of the ssPEEK electrolyte membrane was tested in a fuel cell at 95 A degrees C, during which it exhibited a lifetime of more than 1000 h and a slow voltage degradation of 18 mu V h(-1) at a current density of 0.3 A cm(-2). After durability test, the catalyst layers were analyzed by X-ray diffraction (XRD) and transmission electron microscopy (TEM); the polymer electrolyte membrane was investigated by determining the change in thickness, proton conductivity, and amounts of sulfonic acid groups. It was concluded that the degradation of performance in fuel cell was due to the thermal aging of the hydrocarbon polymer electrolyte membrane being exposed to the electrochemical environment with the pure oxygen acting as the oxidant gas, as well as the Nafion-based catalyst layer being subjected to high temperature for a long time, where the Pt catalyst was aggregated and sintered. |
| URI | http://hdl.handle.net/20.500.11897/247058 |
| ISSN | 0022-2461 |
| DOI | 10.1007/s10853-009-3490-z |
| Indexed | SCI(E) EI |
| Appears in Collections: | å å¦ä¸ å å å·¥ç¨ å¦é ¢ |
