| Title | Comparable hydrogen isotopic fractionation of plant leaf wax n-alkanoic acids in arid and humid subtropical ecosystems |
| Authors | Gao, Li Zheng, Mei Fraser, Matthew Huang, Yongsong |
| Affiliation | Brown Univ, Dept Geol Sci, Providence, RI 02912 USA. Peking Univ, Coll Environm Sci & Engn, Beijing 100871, Peoples R China. Arizona State Univ, Global Inst Sustainabil, Tempe, AZ USA. GeoIsoChem Corp, Civina, CA 91722 USA. |
| Keywords | leaf waxes hydrogen isotope fractionation ecosystems comparable arid humid DELTA-D VALUES STABLE CARBON D/H RATIOS ATMOSPHERIC AEROSOLS LIPID BIOMARKERS SURFACE SEDIMENT LAKE-SEDIMENTS RECORD CLIMATE TERRESTRIAL |
| Issue Date | 2014 |
| Publisher | geochemistry geophysics geosystems |
| Citation | GEOCHEMISTRY GEOPHYSICS GEOSYSTEMS.2014,15,(2),361-373. |
| Abstract | Leaf wax hydrogen isotope proxies have been widely used to reconstruct past hydrological changes. However, published reconstructions have given little consideration for the potentially variable hydrogen isotopic fractionation relative to precipitation (epsilon wax-p) under different climate and environmental settings. Chief among various potential factors controlling fractionation is relative humidity, which is known to strongly affect oxygen isotopic ratios of plant cellulose, but its effect on hydrogen isotopic fractionation of leaf waxes is still ambiguous. Analyses of lake surface sediments and individual modern plants have provided valuable information on the variability of epsilon wax-p, but both approaches have significant limitations. Here, we present an alternative method to obtain the integrated, time-resolved ecosystem-level epsilon wax-p values, by analyzing modern aerosol samples collected weekly from arid (Arizona lowlands) and humid subtropical (Atlanta, Georgia) environments during the main growth season. Because aerosol samples mainly reflect regional leaf wax resources, the extreme contrast in the hydroclimate and associated vegetation assemblages between our study sites allows us to rigorously assess the impact of relative humidity and associated vegetation assemblages on leaf wax hydrogen isotopic fractionation. We show there is only minor difference (mostly <10 parts per thousand) in the mean epsilon wax-p values in the two end-member environments. One possible explanation is that the positive isotopic effects of low relative humidity are offset by progressive replacement of trees with grasses that have a more negative apparent fractionation. Our results represent an important step toward quantitative interpretation of leaf wax hydrogen isotopic records. |
| URI | http://hdl.handle.net/20.500.11897/216952 |
| ISSN | 1525-2027 |
| DOI | 10.1002/2013GC005015 |
| Indexed | SCI(E) EI |
| Appears in Collections: | 环境科学与工程学院 |
