Title Control of Carrier Type and Density in Exfoliated Graphene by Interface Engineering
Authors Wang, Rui
Wang, Shengnan
Zhang, Dongdong
Li, Zhongjun
Fang, Ying
Qiu, Xiaohui
Affiliation Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China.
Peking Univ, Acad Adv Interdisciplinary Studies, Beijing 100871, Peoples R China.
Tsinghua Univ, Dept Phys, Beijing 100084, Peoples R China.
Keywords graphene
interface
doping
Raman
Fermi level
SELF-ASSEMBLED MONOLAYERS
FEW-LAYER GRAPHENE
RAMAN-SPECTROSCOPY
SUSPENDED GRAPHENE
CHARGE
FIELD
POLARIZABILITY
TRANSISTORS
MEMBRANES
FILMS
Issue Date 2011
Publisher acs nano
Citation ACS NANO.2011,5,(1),408-412.
Abstract Air stable n-doped or p-doped grapliene sheets on a chip were achieved by modifying the substrates with self-assembled layers of silaile and polymer. The interfacial effects on the electronic properties of graphene were investigated using micro Raman and Kelvin probe force microscopy (KPFM). Raman studies demonstrated that the phonon vibrations were sensitive to the doping level of graphene on the various substrates. Complementary information on the charge transfer between the graphene and substrate was extracted by measuring the surface potential of graphene flakes using KPFM, which Illustrated the distribution of carriers indifferent graphene layers as well as the formation of dipoles at the interface. The Fermi level of single layer graphene an the modified substrates could be tuned in a range from - 130 to 90 mV with respect to the Dirac point, corresponding to the doped carrier concentrations up to 10(12) cm(-2).
URI http://hdl.handle.net/20.500.11897/164148
ISSN 1936-0851
DOI 10.1021/nn102236x
Indexed SCI(E)
EI
Appears in Collections: 前沿交叉学科研究院

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